Carboranes ..................................................................................................................................... 407 Metal Carbonyl Clusters- Low Nuclearity Carbonyl Clusters....................................................... 412 Total Electron Count (TEC) .......................................................................................................... 417 Problems ........................................................................................................................................ 424 Bibliography ..................................................................................................................................
425 CHAPTER 11 ................................................................................................................................. 426 Metal-Π Complexes: ............................................................................................................................ 426 Metal Carbonyls: Structure and Bonding ...................................................................................... 426 Vibrational Spectra of Metal Carbonyls for Bonding and Structure Elucidation .......................... 439 Important Reactions of Metal Carbonyls .......................................................................................
446 Preparation, Bonding, Structure and Important Reactions of Transition Metal Nitrosyl, Dinitrogen and Dioxygen Complexes .............................................................................................................. 450 Tertiary Phosphine as Ligand ........................................................................................................ 463 Problems ........................................................................................................................................ 469 Bibliography ..................................................................................................................................
470 INDEX ............................................................................................................................................. 471