CHAPTER 8 ................................................................................................................................... 214 Electronic Spectra of Transition Metal Complexes: .................................................................... 214 Spectroscopic Ground States ......................................................................................................... 214 Correlation and Spin-Orbit Coupling in Free Ions for 1st Series of Transition Metals ................. 243 Orgel and Tanabe-Sugano Diagrams for Transition Metal Complexes ( d 1 d 9 States) ................
248 Calculation of Dq, B and β Parameters ......................................................................................... 280 Effect of Distortion on the d -Orbital Energy Levels ..................................................................... 300 Structural Evidence from Electronic Spectrum ............................................................................. 307 Jahn-Tellar Effect .......................................................................................................................... 312 Spectrochemical and Nephelauxetic Series ...................................................................................
324 Charge Transfer Spectra ................................................................................................................ 328 Electronic Spectra of Molecular Addition Compounds ................................................................. 336 Problems ........................................................................................................................................ 340 Bibliography ..................................................................................................................................
341 CHAPTER 9 ................................................................................................................................... 342 Magnetic Properties of Transition Metal Complexes: ................................................................. 342 Elementary Theory of Magneto-Chemistry ................................................................................... 342 Guoy’s Method for Determination of Magnetic Susceptibility ..................................................... 351 Calculation of Magnetic Moments ................................................................................................
354 Magnetic Properties of Free Ions ................................................................................................... 359 Orbital Contribution: Effect of Ligand-Field ................................................................................ 362 Application of Magneto-Chemistry in Structure Determination ................................................... 370 Magnetic Exchange Coupling and Spin State Cross Over ............................................................ 375 Problems ........................................................................................................................................
384 Bibliography .................................................................................................................................. 385 CHAPTER 10 ................................................................................................................................. 386 Metal Clusters: ...................................................................................................................................... 386 Structure and Bonding in Higher Boranes .....................................................................................
386 Wade’s Rules ................................................................................................................................. 401