CHAPTER 4 ..................................................................................................................................... 96 Reaction Mechanism of Transition Metal Complexes – II: ...................................................... 96 Mechanism of Ligand Displacement Reactions in Square Planar Complexes ................................ 96 The Trans Effect .............................................................................................................................. 98 Theories of Trans Effect ................................................................................................................
103 Mechanism of Electron Transfer Reactions – Types; Outer Sphere Electron Transfer Mechanism and Inner Sphere Electron Transfer Mechanism .................................................................................. 106 Electron Exchange ......................................................................................................................... 117 Problems ........................................................................................................................................ 121 Bibliography ..................................................................................................................................
122 CHAPTER 5 ................................................................................................................................... 123 Isopoly and Heteropoly Acids and Salts: ........................................................................................ 123 Isopoly and Heteropoly Acids and Salts of Mo and W: Structures of Isopoly and Heteropoly Anions ............................................................................................................................................123 Problems ........................................................................................................................................
152 Bibliography .................................................................................................................................. 153 CHAPTER 6 ................................................................................................................................... 154 Crystal Structures: ...............................................................................................................................
154 Structures of Some Binary and Ternary Compounds Such as Fluorite, Antifluorite, Rutile, Antirutile, Crystobalite, Layer Lattices - CdI 2 , BiI 3 ; ReO 3 , Mn 2 O 3 , Corundum, Pervoskite, Ilmenite and Calcite.............................................................................................................................................154 Problems ........................................................................................................................................ 178 Bibliography ..................................................................................................................................
179 CHAPTER 7 ................................................................................................................................... 180 Metal-Ligand Bonding: ....................................................................................................................... 180 Limitation of Crystal Field Theory ................................................................................................ 180 Molecular Orbital Theory – Octahedral, Tetrahedral or Square Planar Complexes ...................... 184 π-Bonding and Molecular Orbital Theory .....................................................................................
198 Problems ........................................................................................................................................ 212 Bibliography .................................................................................................................................. 213